October 5, 2024
PET

TMP

TMP

TMP

Trimethylolpropane = TMP = Tripropane = Hexaglycerin = 1,1,1-Trimethylolpropane
CAS Number: 77-99-6
EC Number: 201-074-9

EC / List no.: 201-074-9
CAS no.: 77-99-6
Mol. formula: C6H14O3

1,1,1-TRIMETHYLOLPROPANE
Tris(hydroxymethyl)propane
2-Ethyl-2-(hydroxymethyl)-1,3-propanediol
Propylidynetrimethanol
Hexaglycerol
Hexaglycerine
CAS #: 77-99-6
EC Number: 201-074-9

Use of TMP
Paint resin
Urethane resin
Setting resin by UV ray
Synthetic lubricating oil ( Trimethylolpropane (TMP) ester is an eco-friendly lubricant that fully biodegradable and known as bio lubricant.)
Coating resins
Neo polyol esters
Multifunctional acrylates
Polyether polyols for urethanes

Trimethylolpropane is a trifunctional alcohol with a wide spectrum of applications in the chemical industry, e.g. for the synthesis of alkyd and polyester resins, synthetic lubricants, PU-foams and lacquers or glues and adhesives.
Furthermore trimethylol propane is used for the production of dyestuffs, pigments, paints and silicone products.

Synonym: 2-Ethyl-2-hydroxymethyl-1,3-propanediol, Trimethylolpropane

CAS Number: 77-99-6 Linear Formula CH3CH2C(CH2OH)3
Molecular Weight: 134.17
Beilstein/REAXYS Number: 1698309
EC Number: 201-074-9
MDL number: MFCD00004694
PubChem Substance
ID 24848880
NACRES NA.22

Trimethylolpropane is a white solid in flake or powder form at ambient temperatures.
Liquid form trimethylolpropane is colorless and has a mild odor.

Trimethylolpropane (TMP) is the organic compound with the formula CH3CH2C(CH2OH)3.
This colourless to white solid with a faint odor is a triol.
Containing three hydroxy functional groups, TMP is a widely used building block in the polymer industry.

Uses: Trimethylolpropane is used as an additive or intermediate in the manufacture of alkyd and polyester resins, synthetic lubricants, polyurethane foams, lacquers, glues, adhesives, dyes, pigments, paints and silicone products.

Trimethylolpropane (TMP) is a colorless hygroscopic solid crystal that is soluble in water and alcohol.
TMP is widely used as a building block in the polymer industry.
Trimethylolpropane (TMP) is also used as a conditioning agent, manufacture of varnishes, alkyd resins, synthetic drying oils, urethane foams and coatings, silicone lubricant oils, lactone plasticizers, textile finishes, surfactants, and epoxy products.

Description
Application
1,1,1-Tris(hydroxymethyl)propane was used as hydrogen bond-donating agent during triol-promoted activation of the C-F bond of benzylic fluorides.
Trimethylolpropane was used in synthesis of new octanuclear manganese cluster and hyperbranched polyethers .

Trimethylolpropane
Product details
Trimethylolpropane (TMP) is an alcohol and is being produced by the reaction of Formaldehyde with n-Butyraldehyde.
Trimethylolpropane is a intermediate product of the synthetic of polyetherpolyole, polyesterpolyole and polyurethane.
Trimethylolpropane is an triol.

CAS-No. 77-99-6
EINECS-No. 201-074-9
Chemical formula: C6H14O3

Synonym: Hexaglycerol | TMP | 2-(hydroxymethyl)-2-ethylpropane-1,3-diol | 2-ethyl-2-hydroxymethyl-1,3-propanediol
Uses/applications: Polyurethane-foams and Coatings, Polyesterpolyol, Polyester and Alkyd resins, Glues, Lubricating Oils.

Trimethylolpropane is an organic compound that contains three hydroxyl group.
Trimethylolpropane is widely used as a building block by the polymer industry.
Trimethylolpropane is white in colour and solid at room temperature.
Hexaglycerin ( TMP) melts into a colourless liquid at 59oC and is soluble in water as well as organic solvents such as alcohols.
However, Trimethylolpropane is not soluble in benzene.
Trimethylolpropane is highly stable against light and other environmental influences.
The structure of trimethylolpropane makes it well-balanced and flexible for use in products.
Trimethylolpropane is highly stable against oxidation, hydrolysis and pyrolysis. It can improve the strength of a product and make it corrosion resistant.
Trimethylolpropane is a widely used raw material for the production of alkyd resins, polyurethane coatings and for other high-end coatings.
Trimethylolpropane can also be used in the manufacturing of various plasticizers, lubricants, heat insulators, surfactants, etc. It is also used in the production of paints, pigments and dyestuff. Trimethylolpropane is used in the electrical industry as it offers insulation. It is also used for making glues and adhesives. Trimethylolpropane is a key raw material in the production of Trimethylolpropane Methacrylate (TMPTM) and Trimethylolpropane Triacrylate (TMPTA). Due to its wide range of applications in various industries, its demand in the market is gaining traction. Increase in the demand for trimethylolpropane has led to a rise in its production.

Trimethylolpropane flakes
Trimethylolpropane (TMP) is a trifunctional alcohol supplied in solid form

Adhesives and Sealants
Trimethylolpropane (TMP) is used in the production of adhesive resins such as (polyurethanes polyester polyol and polycarbonate diol).

Coatings
Trimethylolpropane (TMP) is used as a precursor for the manufacture of resins including alkyds, saturated polyesters and  polyurethanes (polyester polyol and polycarbonate diol).
Due to its structure, TMP imparts high UV and chemical resistance .

TriMethylolPropane(TMP) (TMP) is important organic chemical industry’s intermediate fine chemical product.
Because its unique chemical structure, TriMethylolPropane(TMP) can improve soundness, erosion resistance and the stopping property of resin, for hydrolysis, pyrolysis and oxidation satisfactory stability is arranged, main raw material as Synolac, urethane resin and high-grade paint/coating also can be used for softening agent, tensio-active agent, quality lubricant, synthetic leather and lagging material etc.

Use: TMP is widely used as a building block in the polymer industry.
Trimethylolpropane is also used as a conditioning agent, manufacture of varnishes, alkyd resins, synthetic drying oils, urethane foams and coatings, silicone lubricant oils, lactone plasticizers, textile finishes, surfactants, and epoxy products.

Trimethylolpropane is a chemical compound used in the production of plastic polymers.
All kinds of plastic material is derived from plastic polymers, from wearable polyester to usable polyethylene. The main thing which is related to these compounds is their structural rigidity because of strong and coherent chemical bonds. Yet, they are completely malleable. The weather, heat and gas resistance of plastics make them the first choice of many industries.

TMP has three hydroxyl groups.
Trimethylolpropane  is a white material in flakes.
TMP is used in saturated polyesters for coil coatings, alkyds for paints, polyurethanes for coatings and elastomers, acrylic acid esters for radiation curing, esters for synthetic lubricants, rosin esters and for surface treatment of pigments.

Trimethylolpropane flakes Performance advantages for your polyester resins Performance advantages for your polyester resins

Product Description
Trimethylolpropane (TMP) is a polyhydric alcohol that has three equally reactive hydroxyl groups making it a versatile building block with crosslinking capabilities for polyesters, polyurethanes and acrylates.
In liquid polyesters, alkyds and polyurethanes TMP is used to give additional crosslinking enabling increased resistance of your coating.
TMP acrylate is also well known to be a perfect fit as an acrylate in UV wood coatings combining low viscosity with high scratch resistance.
Another application benefitting from TMP is synthetic lubricants where polyesters are used in for example engine, transmission, hydraulic and metal working oils to give low viscosity and increased intrinsic viscosity.
Trimethylolpropane is a white material in flakes.

Trimethylolpropane is used in a large variety of commercial applications, including in the manufacturer of varnishes, resins; polyesters for polyurethane foams, textile finishes, plastictzers, and cross-linking agents for spandex fibers.

PRODUCTION OF Trimethylolpropane:
Process comments : Formaldehyde + Sodium hydroxide + Butyl aldehyde (Reaction) -> Condensation -> Extraction -> Product -> Purification Continuous closed systems

Uses: Alkyd resins for coatings, polyesters resins , Silicone, Acrylates, Adhesives and sealants, Electric insulation coatings, Pigments, Ink, Toner, and Colorant Products, Fabric, Textile, and Leather Products, Food Packaging, production of flexible polyurethanes, PU resin.

Applications
Acrylates
Alkyd resins
Chemical Industry
Chemical synthesis
Coating
Dyestuffs, pigments and optical brighteners
Electric insulation coating
Energy
Glues and adhesives
Hardener and crosslinking agents for polymeres
Lubricants and oils
Manufacturing of coating
Manufacturing of dyestuffs
Manufacturing of glues and adhesives
Manufacturing of peroxides
Manufacturing of pigments
Manufacturing of plastics
Manufacturing of printing inks
Petrochemicals
Petroleum
Pigments
Plastic- and Rubberpolymers
Polyester
Polyester resins
Polyethers/polyoles
Polymer auxiliaries
Polyurethane resins
Polyurethanes
Silicon products
Specialities
Synthetic lubricants
Textile auxiliaries
Textile industry

Synonyms
2,2-Bis-hydroxymethyl-1-butanol
2-Ethyl-2-hydroxymethyl-1,3-propanediol
Hexaglycerin
TMP
Trimethylolpropane
1,1,1-Trimethylolpropane
Tripropane
1,1,1-Tris(hydroxymethyl)propane

Trimethylolpropane Chemical Properties, Uses and Production

Chemical Properties
Trimethylolpropane is a Colorless, hygroscopic crystals. Soluble in water and alcohol. Combustible.The three primary hydroxyl groups undergo the normal OH group reactions.

Uses
Conditioning agent, manufacture of varnishes, alkyd resins, synthetic drying oils, urethane foams and coatings, silicone lubricant oils, lactone plasticizers, textile finishes, surfactants, epoxidation products.

Uses
Large quantities of trimethylolpropane and its ethoxylated derivatives are used as precursors for urethanes and polyester resins. Another important field of application is in medium-oil and short-oil alkyd resins (→Alkyd Resins). The resulting lacquers are characterized by excellent resistance to alkali, detergents, and water, combined with outstanding impact resistance and flexibility, as well as excellent clearness and clearness retention.
Reaction products with fatty acids (C5 –C10) are components of synthetic lubricants. A strongly growing market will be the use of these blended polyol esters in chlorine-free, purely fluorocarbon based refrigerant systems. Powder and high-solids coatings represent a strong potential market for TMP, because it contributes to low viscosity. TMP acrylates are used as reactive diluents in UV-cured systems for inks and coatings, and TMP allyl ethers in unsaturated polyesters.

Chemical Synthesis
Trimethylolpropane is made by the base-catalyzed aldol addition of butyraldehyde with formaldehyde followed by Cannizzaro reaction of the intermediate 2,2-bis(hydroxymethyl) butanal with additional formaldehyde and at least a stoichiometric quantity of base.
synthesis of trimethylolpropane (TMP)

Purification Methods
Crystallise it from acetone and ether and it distils at high vacuum. [Beilstein 1 III 2349.]
Trimethylolpropane Preparation Products And Raw materials

Raw materials
Film evaporator Formaldehyde Butyraldehyde

PRODUCT APPLICATIONS
Petroleum
Plastic- and Rubberpolymers
Polyester
Polyethers polyoles
Petrochemicals
Pigments
Polymer auxiliaries
Polyurethane resins
Polyurethanes
Lubricants and oils
Manufacturing of coating
Silicon products
Glues and adhesives
Chemical Industry
Energy
Dyestuffs pigments and optical brighteners
Textile auxiliaries
Textile industry
Synthetic lubricants
Hardener and crosslinking agents for polymeres
Specialities
Manufacturing of glues and adhesives
Manufacturing of dyestuffs
Manufacturing of peroxides
Manufacturing of pigments
Manufacturing of printing inks
Manufacturing of plastics
Acrylates
Alkyd resins
Coating
Chemical synthesis
Polyester resins
Electric insulation coating
Electric insulation coating

SYNONYMS
2,2-Bis-hydroxymethyl-1-butanol
2-Ethyl-2-hydroxymethyl-1,3-propanediol
Hexaglycerin
TMP
Trimethylolpropane
1,1,1-Trimethylolpropane
Tripropane
1,1,1-Tris(hydroxymethyl)propane

Production
TMP is produced via a two step process, starting with the condensation of butanal with formaldehyde:

CH3CH2CH2CHO + 2 CH2O → CH3CH2C(CH2OH)2CHO
The second step entails a Cannizaro reaction:

CH3CH2C(CH2OH)2CHO + CH2O + NaOH → CH3CH2C(CH2OH)3 + NaO2CH.
Approximately 200,000,000 kg are produced annually in this way.

Applications
TMP is mainly consumed as a precursor to alkyd resins.
Otherwise, acrylated and alkoxylated TMP’s are used as multifunctional monomers to produce various coatings, Ethoxylated and propoxylated TMP, derived condensation of from TMP and the epoxides, are used for production of flexible polyurethanes.
Allyl ether derivatives of TMP, with the formula CH3CH2C(CH2OCH2CH=CH2)3-x(CH2OH)x are precursors to high-gloss coatings and ion exchange resins.
The oxetane “TMPO” is a photoinduceable polymerisation initiator.

Preferred IUPAC name: 2-Ethyl-2-(hydroxymethyl)propane-1,3-diol
Other names: TMP, 2-ethyl-2-hydroxymethyl-1,3-propanediol

Identifiers
CAS Number: 77-99-6
EC Number: 201-074-9

Properties
Chemical formula: C6H14O3
Molar mass: 134.17 g/mol
Appearance: White solid
Odor: Faint odor
Density: 1.084 g/mL
Melting point: 58 °C (136 °F; 331 K)
Boiling point: 289 °C (552 °F; 562 K)
Solubility in water at 20°C: miscible
Relative vapour density (air = 1): 4.63
Flash point: 172°C c.c.
Auto-ignition temperature: ~375°C
Explosive limits, vol% in air: 2.0-11.8
Octanol/water partition coefficient as log Pow: -0.5

Hazards
NFPA 704 (fire diamond)
NFPA 704 four-colored diamond
Flash point: 172 °C (342 °F; 445 K)

Trimethylolpropane (TMP, IUPAC name 2-(hydroxymethyl)-2-ethylpropane-1,3-diol) and its ethoxylated derivatives are extensively used as precursors for urethanes and polyester resins.

1,1,1-tris(hydroxymethyl)propane
trimethylolpropane

Trimethylolpropane
77-99-6
2-ethyl-2-(hydroxymethyl)propane-1,3-diol
Trimethylol propane
2-Ethyl-2-(hydroxymethyl)-1,3-propanediol
Ethriol
Hexaglycerine
Ettriol
1,1,1-TRIS(HYDROXYMETHYL)PROPANE
Etriol
1,3-Propanediol, 2-ethyl-2-(hydroxymethyl)-
TMP (alcohol)
Ethyltrimethylolmethane
1,1,1-Trimethylolpropane
Tri(hydroxymethyl)propane
2,2-Bis(hydroxymethyl)-1-butanol
Methanol, (propanetriyl)tris-
Tris(hydroxymethyl)propane
1,1,1-Tri(hydroxymethyl)propane
2-Ethyl-2-(hydroxymethyl)propanediol
UNII-090GDF4HBD
NSC 3576
Propane, 1,1,1-tris(hydroxymethyl)-
2-Ethyl-2-hydroxymethyl-1,3-propanediol
090GDF4HBD
MFCD00004694
Propylidynetrimethanol
HSDB 5218
2-Ethyl-2-(hydroxymethyl)-1,3-propanediol, 98%
EINECS 201-074-9
BRN 1698309
AI3-24124
trimethylol-propane
9D2
1,1-Trimethylolpropane
ACMC-1BNS1
DSSTox_CID_6448
EC 201-074-9
DSSTox_RID_78116
DSSTox_GSID_26448
Oprea1_508416
Propanediol, 2-ethyl-2-(hydroxymethyl)-, 1,3-
SCHEMBL15026
4-01-00-02786 (Beilstein Handbook Reference)
1,1-Tris(hydroxymethyl)propane
CHEMBL3185136
DTXSID2026448
NSC3576
1, 2-ethyl-2-(hydroxymethyl)-
Propane,1,1-tris(hydroxymethyl)-
ZINC388288
Butanol, 2,2-bis(hydroxymethyl)-
AMY25779
NSC-3576
Tox21_200028
ANW-37143
BBL012231
SBB061433
STL163569
AKOS005715709
MCULE-6600552830
NE10346
CAS-77-99-6
NCGC00248497-01
NCGC00257582-01
1,1,1-Tris(hydroxymethyl)propane, 97%
Ethyl-2-(hydroxymethyl)-1,3-propanediol
K377
VS-03244
2-Ethyl-2-hydroxymethyl-propan-1,3-diol
2-ethyl-2-hydroxymethyl-propane-1,3-diol
2-(hydroxymethyl)-2-ethylpropane-1,3-diol
FT-0605956
ST51047451
2-ethyl-2-hydroxymethyl-1,3-dihydroxypropane
55367-EP2371805A1
Q161270
F0001-1980
Z1815149363
1,1,1-Tris(hydroxymethyl)propane, dist., >=98.0% (GC)
59359-44-3

1,1,1-Trimethylolpropane
1,3-Propanediol, 2-ethyl-2-(hydroxymethyl)- [ACD/Index Name]
1698309 [Beilstein]
201-074-9 [EINECS]
2-Ethyl-2-(hydroxymethyl)-1,3-propandiol [German] [ACD/IUPAC Name]
2-Ethyl-2-(hydroxymethyl)-1,3-propanediol [ACD/IUPAC Name]
2-Éthyl-2-(hydroxyméthyl)-1,3-propanediol [French] [ACD/IUPAC Name]
2-Ethyl-2-hydroxymethyl-1,3-propanediol
77-99-6 [RN]
MFCD00004694 [MDL number]
Q1X2&1Q1Q [WLN]
Trimethylolpropane [Wiki]
TY6470000
1,1,1-Tri(hydroxymethyl)propane
1,1,1-Tri(hydroxymethyl)propane; 1,1,1-Trimethylolpropane; 1,1,1-Tris(hydroxymethyl)propane; 2,2-Bis(hydroxymethyl)-1-butanol; 2-(Hydroxymethyl)-2-ethyl-1,3-propanediol
1,1,1-trimethylolpropane 97%
1,1,1-Trimethylolpropane, propoxylated
1,1,1-tris(hydroxymethyl)propane (tmp)
1,1,1-tris(hydroxymethyl)propane 98%
1,1,1-Tris(hydroxymethyl)propane-d5
101377-62-2 [RN]
103782-76-9 [RN]
2-(Hydroxymethyl)-2-ethyl-1,3-propanediol
2-(hydroxymethyl)-2-ethylpropane-1,3-diol
2,2-Bis(hydroxymethyl)-1-butanol
2,5-dimethylthiophene-3-carbaldehyde
2-ethyl-2-(hydroxymethyl) 1,3-propanediol
2-Ethyl-2-(hydroxymethyl)-1, 3-propanediol
2-ethyl-2-(hydroxymethyl)-1,3-propanediol, 98%
2-Ethyl-2-(hydroxymethyl)propanediol
2-Ethyl-2-hydroxymethyl-propane-1,3-diol
2-ethyl-2-methylol-propane-1,3-diol
4-01-00-02786 (Beilstein Handbook Reference) [Beilstein]
824-11-3 [RN]
9D2
Butan-1-ol, 2,2-bis(hydroxymethyl)-
butane-1,1,1-triol
Butanol, 2,2-bis(hydroxymethyl)-
c6h14o3
EINECS 201-074-9
Ethriol
ethyl-2-(hydroxymethyl)-1,3-propanediol
Ethyltrimethylolmethane
Etriol
Ettriol
Hexaglycerine
Hexaglycerol
http:////www.amadischem.com/proen/605114/
Methanol, (propanetriyl)tris-
METHANOL, [(1,1-DIMETHYLPROPYL)DIOXY]-
MFCD00152500
Oprea1_508416
Propane, 1,1,1-tris(hydroxymethyl)-
Propylidynetrimethanol
Propylidynetris(methanol), 1,1,1-Trimethylolpropane, 1,1,1-Tris(hydroxymethyl)propane
TMP
Tri(hydroxymethyl)propane
Trimethylol propane
trimethylolpropane, ???
Tris(hydroxymethyl)propane
VS-03244

CAS No.77-99-6
Chemical Name:Trimethylolpropane
SynonymsEtriol;Ethriol;Ettriol;Trimethylol;1,1,1-tris(;TMPHYDRO(R);Abbreviation;tmp(alcohol);tmp[alcohol];HEXAGLYCEROL
CBNumber:CB3725999
Molecular Formula:C6H14O3
Formula Weight:134.17
MOL File:77-99-6.mol

1,1,1-TRIS(HYDROXYMETHYL)PROPANE, DIST.
TrimethanolPropane
1,3-Propanediol, 2-ethyl-2-(hydroxymethyl)-
Trimethylol
Abbreviation
propylidynetrimethanol
Trimethylolpropane, carbamate with tolylene diisocyanate solution
Trimethyloy propane
TRIMETHYLOLPROPANE(TMP)
1,1,1-Tris(hydroxymethy1)propane
TRIMETHYLOLPROPANE (2-ETHYL-2-HYDROXYMETHYLPROPANE) TMP
2-ETHYL-2-HYDROXYMETHYLPROPANE-1,3-DIOL
Trimethylolpropan
Perstorp Trimethylolpropane (TMP)
2-Ethyl-2-hydroxymethyl-1,3-propanediol, Trimethylolpropane
2-Ethyl-2-(hydroxymethyl)-1,3-propanediol,98%
1,1,1-Propanetriyltrismethanol
1,1′,1”-Propylidynetrimethanol
2-(Hydroxymethyl)-2-ethyl-1,3-propanediol
1,1,1-tris(hydroxymethyl)propane /Hexaglycerine
TRIS(HYDROXYMETHYL)PROPANE
(propanetriyl)tris-methano
1,1,1-Tris(hydroxy)propane
1,1,1-tris(hydroxymethyl)-propan
2,2-bis(hydroxymethyl)-1-butanol[qr]
2,2-Dihydroxymethylbutanol
2-ethyl-2-(hydroxymethyl)-3-propanediol
2-Ethyl-2-(hydroxymethyl)propanediol
1,1,1-tris(
2-ethyl-2-hydroxymethyl-3-propanediol
1,1,1-N-Tris(hydoxymethyl)propane
Trimethylol propane
3-Propanediol,2-ethyl-2-(hydroxymethyl)-1
Butanol, 2,2-bis(hydroxymethyl)-
Ethriol
Ethyltrimethylolmethane
Etriol
Ettriol
Hexaglycerine
Methanol, (propanetriyl)tris-
Propane, 1,1,1-tris(hydroxymethyl)-
TMP (Alcohol)
tmp(alcohol)
tmp[alcohol]
Tri(hydroxymethyl)propane
2,2-Bis(hydroxymethyl)-1-butanol 2-Ethyl-2-hydroxymethyl-1,3-propanediol Hexaglycerol 1,1,1-Tris(hydroxymethyl)propane
2-ETHYL-2-(HYDROXYMETHYL)-1,3-PROPANEDIO
TMP, TriMethylol propane
1,1,1-Tris(hydroxyMethyl)propane (TMP)
2-Ethyl-2-(hydroxyMethyl)-1,3-propanediol, 98% 1KG
2-Ethyl-2-(hydroxyMethyl)-1,3-propanediol, 98% 500GR
1,1,1-Tris(hydroxymethyl)propane dist., >=98.0% (GC)
2-Ethyl-2-(hydroxymethyl)-1,3-propanediol for synthesis
HEXAGLYCEROL
2,2′-DIHYDROXYMETHYL-1-BUTANOL
2,2-BIS(HYDROXYMETHYL)-1-BUTANOL
2-ETHYL-2-(HYDROXYMETHYL)-1,3-PROPANEDIOL
1,1,1-TRIS(HYDROXYMETHYL)PROPANE

1,1,1-trimethylolpropane
1,1,1-Tris(hydroxymethyl)propane
Propylidynetrimethanol
propylidynetrimethanol

CAS names
1,3-Propanediol, 2-ethyl-2-(hydroxymethyl)-

IUPAC names
1,1,1-trimethylolpropane
1,1,1-Trimethylolpropane (TMP)
1,1,1-Tris(hydroxymethyl)propane
1,3-Propanediol, 2-ethyl-2-(hydroxymethyl)-
2,2-Dihydroxymethylbutanol-1 (NAM;SYN)
2-(hydroxymethyl)-2-ethylpropane-1,3-diol
2-ethyl-2-(hydroxymethyl) propane-1,3diol
2-ethyl-2-(hydroxymethyl)propane-1,3-diol
2-Ethyl-2-hydroxymethyl-1,3-propandiol
Propylidynetrimethanol
propylidynetrimethanol
Propylidynetrimethanol
propylidynetrimethanol
TMP
Trimethylol propane
Trimethylol propane
TRIMETHYLOLPROPAN
Trimethylolpropan
TRIMETHYLOLPROPANE
Trimethylolpropane
trimethylolpropane
TRIMETHYLOLPROPANE
Trimethylolpropane
TRIMETHYLPROPANE
Trimethylpropane
Trimethylpropane (CAS 77-99-6)

Trade names
1,1,1-Tri(hydroxymethyl)propane
1,1,1-TRIMETHYLOLPROPAN
1,1,1-Trimethylolpropane
1,1,1-TRIS(HYDROXYMETHYL)PROPAN
1,1,1-Tris(hydroxymethyl)propane
1,3-PROPANEDIOL, 2-ETHYL-2-(HYDROXYMETHYL)-
1,3-Propanediol, 2-ethyl-2-(hydroxymethyl)-
1,3-Propanediol, 2-ethyl-2-(hydroxymethyl)- (8CI, 9CI)
2,2-Bis(hydroxymethyl)-1-butanol
2,2-DIHYDROXYMETHYLBUTANOL-1
2-Ethyl-2-(hydroxymethyl)-1,3-propanediol
2-ETHYL-2-(HYDROXYMETHYL)PROPAN-1.3-DIOL
2-Ethyl-2-(hydroxymethyl)propanediol
Ethriol
ETHYLTRIMETHYLOLMETHAN
Ethyltrimethylolmethane
Ettriol
HEXAGLYCERIN
Propane, 1,1,1-tris(hydroxymethyl)-
PROPYL-1,1,1-TRIS(METHANOL)
RC Crosslinker TR
TMP
TMP (alcohol)
TRIMETHYLOLPROPAN
TRIMETHYLOLPROPANE
Trimethylolpropane
Trimethylolpropane (TMP)
Trimethylpropane
TRIS(HYDROXYMETHYL)PROPAN
Tris(hydroxymethyl)propane

Packaging of TMP

25KG Plastic film bags
500KG Flexible IBC

Synonyms:
2,2-Bis(hydroxymethyl)-1-butanol
2-Ethyl-2-hydroxymethyl-1,3-propanediol
Hexaglycerol
1,1,1-Tris(hydroxymethyl)propane

Description
Overview: Trimethylolpropane is a white solid in flake or powder form at ambient temperatures.
The chemical is shipped and used in a liquid (hot melt) form. Liquid form trimethylolpropane is colorless and has a mild odor.
Uses: Trimethylolpropane is used as an additive or intermediate in the manufacture of alkyd and polyester resins, synthetic lubricants, polyurethane foams, lacquers, glues, adhesives, dyes, pigments, paints and silicone products.
Properties: Melting Point:
Boiling Point:138.2°F (58°C) Approx.
Flash Point:579°F (304°C)
Solubility in Water:372°F (189°C) Soluble

Synonyms:
butan-1-ol, 2,2-bis(hydroxymethyl)-
2-    ethyl-2-(hydroxymethyl)-1,3-propanediol
2-    ethyl-2-(hydroxymethyl)propane diol
2-    ethyl-2-(hydroxymethyl)propane-1,3-diol
2-    ethyl-2-hydroxymethyl-1,3-propanediol
2-    ethyl-2-hydroxymethyl-propane-1,3-diol
hexaglycerine
1,1,1-tris(    hydroxymethyl) propane
2,2-bis(    hydroxymethyl)-1-butanol
1,1,1-tris(    hydroxymethyl)propane
methanol, (propanetriyl)tris-
propane, 1,1,1-tris(hydroxymethyl)-
1,3-    propanediol, 2-ethyl-2-(hydroxymethyl)-
propanediol, 2-ethyl-2-(hydroxymethyl)-, 1,3-
propylidynetrimethanol
tri(hydroxymethyl)propane
1,1,1-    tri(hydroxymethyl)propane
trimethylol propane
1,1,1-    trimethylolpropane

Ethriol
2-Ethyl-2-(hydroxymethyl)propanediol
2-Ethyl-2-(hydroxymethyl)-1,3-propanediol
Ethyltrimethylolmethane
Ettriol
Hexaglycerine
Propane, 1,1,1-tris(hydroxymethyl)- TMP
TMP (alcohol) 1,1,1-Tri(hydroxymethyl)propane
1,1,1-Trimethylolpropane Tris(hydroxymethyl)propane
1,1,1-Tris(hydroxymethyl)propane

WHAT IS TRIMETHYLOL PROPANE ?

Synonyms: Trimethylolpropane, 77-99-6, 2-ethyl-2-(hydroxymethyl)propane-1,3-diol, Ethriol, Trimethylol propane, 2-Ethyl-2-(hydroxymethyl)-1,3-propanediol, Hexaglycerine, Ettriol, Etriol, 1,3-Propanediol, 2-ethyl-2-(hydroxymethyl)-, TMP (alcohol), 1,1,1-TRIS(HYDROXYMETHYL)PROPANE, Ethyltrimethylolmethane, 1,1,1-Trimethylolpropane, Tri(hydroxymethyl)propane, 2,2-Bis(hydroxymethyl)-1-butanol, Methanol, (propanetriyl)tris-, Tris(hydroxymethyl)propane, 1,1,1-Tri(hydroxymethyl)propane, Propylidynetrimethanol
INCI: Trimethylol Propane
Chemical Formula: C6H14O3
CAS Number: 77-99-6

Trimethylolpropane
Agent Name
Trimethylolpropane

CAS Number
77-99-6

Formula
C6-H14-O3

Major Category
Other Classes
Trimethylolpropane formula graphical representation

Synonyms
1,1,1-Tri(hydroxymethyl)propane; 1,1,1-Trimethylolpropane; 1,1,1-Tris(hydroxymethyl)propane; 1,3-Propanediol, 2-ethyl-2-(hydroxymethyl)-; 2,2-Bis(hydroxymethyl)-1-butanol; 2-Ethyl-2-(hydroxymethyl)propanediol; Ethriol; Ethyltrimethylolmethane; Etriol; Ettriol; Methanol, (propanetriyl)tris-; Propane, 1,1,1-tris(hydroxymethyl)-; TMP; TMP (VAN); TMP (alcohol); Tri(hydroxymethyl)propane; Tris(hydroxymethyl)propane; Propylidynetrimethanol; Propanediol, 2-ethyl-2-(hydroxymethyl)-, 1,3-; [ChemIDplus]

Category
Alcohols and Polyols, Other

Description
Colorless to white hygroscopic solid; [ICSC] White crystalline chunks; [MSDSonline]

Sources/Uses
Used to make varnishes, alkyd resins, polyesters, UV cross linking agents, and esters; Also used in synthetic drying oils, urethane foams and coatings, silicone lube oils, lactone plasticizers, textile finishes, surfactants, epoxidation products, and as a cross-linking agent for spandex fibers; [HSDB] Used to make resins in closed systems; [OECD SIDS: Trimethylolpropane]

Comments
Causes somnolence and respiratory depression in lethal-dose feeding studies of rats and mice; [RTECS] An eye and respiratory tract irritant; [ICSC] May cause irritation; [MSDSonline]

•    az
bنری متیلول پروپان
•    de
1,1,1-Trimethylolpropan
•    e
nTrimethylolpropane
•    fa
نری متیلول پروپان
•    fr
Triméthylolpropane
•    ja
トリメチロールプロパン
•    nl
Trimethylolpropaan
•    sh
Trimetilolpropan
•    sr
Trimetilolpropan
•    zh
1,1,1-三羟甲基丙烷

TMP is used in the production of polyurethanes, synthetic lubricants and coatings.

Trimethylolpropane is a trifunctional alcohol with a wide spectrum of applications in the chemical industry, e.g. for the synthesis of alkyd and polyester resins, synthetic lubricants, PU-foams and lacquers or glues and adhesives. Furthermore trimethylol propane is used for the production of dyestuffs, pigments, paints and silicone products.

The plastic and polymer industry is growing all over the world. As trimethylolpropane is a building block for plastic and polymer, its demand is also increasing. As there is rise in the demand for TMPTM and TMPTA, there is growth in the production of trimethylolpropane. Rise in population and urbanization is leading to the growth of the construction industry and the development of infrastructure, which is contributing to the growth of the paints & coating industry. This is also boosting the demand for trimethylolpropane. Moreover, the growth of the textile, cosmetic and printing industries is also boosting the trimethylolpropane market.

The growth of the petroleum and lubricants market is propelling the trimethylolpropane market as it is used as a fuel additive as well as for the production of lubricants. The growth of the automotive industry is also leading to an increase in the demand for coatings, which is, in turn, boosting the market for trimethylolpropane. In addition, as trimethylolpropane is used for producing insulating wires and cables, its demand is increasing owing to the growth of the electrical industry. Its high stability and flexibility along with its non-corrosive nature has boosted its value in the global market.

However, as it is flammable, it requires proper handling and storage. Its storage facility needs proper ventilation and safety measures. These can act as restraining factors for the market.

Trimethylolpropane Market: Segmentation

The global trimethylolpropane market can be segmented on the basis of its application in various industries, which include the following:

Polymer and Plastic industry
Paints and coating industry
Textile industry
Cosmetics
Fuel and Lubricants
Electrical industry
The global trimethylolpropane market can be segmented on the basis of its applications as follows:

Alkyd Resins
Emulsifier
Plasticizers
Polyester resins
Polyurethane resins
Acrylates
Silicon products
Electric insulation coating
Surfactants
Epoxy products
Fuel additives
Lubricants
Global trimethylolpropane market can also be segmented on the basis of its usage as a raw material in the production of the following:

Trimethylolpropane Triacrylate (TMPTA)
Trimethylolpropane Methaacrylate (TMPTM)
Trimethylolpropane Triesters (TMPTE)
Trimethylolpropane Market: Regional outlook

The plastic and polymer industry in China & India as well as other Asia Pacific countries is growing. The growth of these industries in North America, Latin America, Europe, Middle East and African countries has also been steady. Hence, there is huge demand for trimethylolpropane in these regions because it is a building block for polymer and a key component in plasticizer production. As it is a useful component in the paints and coating industry, its demand will be increase in proportion with the growth of the construction industry and infrastructure development. As population and urbanization is increasing in countries such as China & India, the construction industry in China, India and other Asia Pacific countries along with countries in Latin America is also expected to grow. Regions such as North America, Europe and the Middle East are mainly focused on the development of infrastructure. Therefore, these regions are potential markets for trimethylolpropane.

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